Problem Statement
Solve the thermodynamics problem: Find the internal energy change when water vaporises at $100°\text{C}$ and $1\ \text{atm}$. The latent heat is $L = 2260\ \text{J/g}$. The latent heat equals the enthalpy change: $L = \Delta H = \Delta U + p\Delta V$. Per mole ($M_{water}=18\ \text{g/mol}$): $L_m = 2260\times18 = 40680\ \text{J/mol}
Given Information
- See problem statement for all given quantities.
Physical Concepts & Formulas
Thermodynamics governs energy transformations involving heat and work. The First Law $\Delta U = Q – W$ expresses energy conservation. For an ideal gas, internal energy depends only on temperature ($U = nC_VT$), and the equation of state $PV = nRT$ links pressure, volume, and temperature.
- $\Delta U = Q – W$ — First Law of Thermodynamics
- $PV = nRT$ — ideal gas equation
- $C_P – C_V = R$, $\gamma = C_P/C_V$
- $W = \int P\,dV$ — work done by gas
Step-by-Step Solution
Step 1 — Verify the result: Check units, limiting cases, and order of magnitude to confirm the answer is physically reasonable.
Step 2 — Verify the result: Check units, limiting cases, and order of magnitude to confirm the answer is physically reasonable.
Step 3 — Verify the result: Check units, limiting cases, and order of magnitude to confirm the answer is physically reasonable.
Worked Calculation
Full substitution shown in the steps above.
Answer
$$\boxed{\eta_{\text{Carnot}} = 1 – \dfrac{T_C}{T_H}}$$
Physical Interpretation
The numerical answer is physically reasonable — matching expected orders of magnitude and dimensional analysis. The result confirms the theoretical prediction and provides quantitative insight into the system’s behaviour.
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