Problem 2.57 — Maxwell Distribution: Mean Relative Speed

Problem Statement

Solve the kinematics problem: Find the mean relative speed $\langle v_{rel} \rangle$ of gas molecules of mass $m$ at temperature $T$. For identical molecules, the relative velocity $\mathbf{v}_{rel} = \mathbf{v}_1 – \mathbf{v}_2$ has magnitude distributed as Maxwell with an effective mass $\mu = m/2$ (reduced mass): $$\langle v_

Given Information

  • See problem statement for all given quantities.

Physical Concepts & Formulas

This problem applies fundamental physics principles to the scenario described. The solution requires identifying the relevant conservation laws and equations of motion, then solving systematically with careful attention to units and sign conventions.

  • See the step-by-step solution for the specific equations applied.
  • All quantities are in SI units unless otherwise stated.

Step-by-Step Solution

Step 1 — Verify the result: Check units, limiting cases, and order of magnitude to confirm the answer is physically reasonable.

Step 2 — Verify the result: Check units, limiting cases, and order of magnitude to confirm the answer is physically reasonable.

Step 3 — Verify the result: Check units, limiting cases, and order of magnitude to confirm the answer is physically reasonable.

Worked Calculation

$$\langle v_

Given Information

  • Initial velocity $u$ (or $v_0$)
  • Acceleration $a$ (constant unless stated otherwise)
  • Time $t$ or distance $s$ as given

Physical Concepts & Formulas

Kinematics describes motion without reference to its cause. For constant acceleration, the four SUVAT equations are sufficient to solve any problem. They follow directly from the definitions of velocity ($v = ds/dt$) and acceleration ($a = dv/dt$). For 2D problems (projectile motion), the horizontal and vertical motions are independent — horizontal: constant velocity; vertical: constant acceleration $g$ downward. Relative motion problems require defining a reference frame explicitly and using vector subtraction.

  • $v = u + at$
  • $s = ut + \tfrac{1}{2}at^2$
  • $v^2 = u^2 + 2as$
  • $s = \tfrac{1}{2}(u+v)t$
  • Range of projectile: $R = \dfrac{u^2\sin 2\theta}{g}$
  • Max height: $H = \dfrac{u^2\sin^2\theta}{2g}$

Step-by-Step Solution

Step 1 — List knowns and unknown: $u$, $v$, $a$, $s$, $t$ — identify which three are known.

Step 2 — Choose the SUVAT equation that contains the unknown and all three known quantities.

Step 3 — Substitute and solve algebraically.

Step 4 — For 2D: Decompose $\vec{u}$ into $u_x = u\cos\theta$, $u_y = u\sin\theta$. Solve $x$ and $y$ separately.

Worked Calculation

Substituting all values with units:

Projectile at $u = 20\,\text{m/s}$, $\theta = 30°$:

$$

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Answer

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Answer

$$\boxed{R = \dfrac{u^2\sin 2\theta}{g},\quad H = \dfrac{u^2\sin^2\theta}{2g}}$$

Physical Interpretation

Maxwell’s thermodynamic relations connect seemingly unrelated thermodynamic derivatives, allowing quantities that are hard to measure directly (like entropy changes at constant pressure) to be computed from measurable ones.


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