Problem Statement
Solve the thermodynamics problem: Solve the work-energy problem: One mole of a van der Waals gas expands isothermally at $T=300\ \text{K}$ from $V_1=1.0\ \text{L}$ to $V_2=10\ \text{L}$. The constants are $a=0.136\ \text{J·m}^3/\text{mol}^2$, $b=38.5\ \text{cm}^3/\text{mol}$. Find the work done and compare with the ideal gas value.
Given Information
- See problem statement for all given quantities.
Physical Concepts & Formulas
The van der Waals equation of state corrects the ideal gas law for finite molecular volume and intermolecular attractions. The parameter $a$ accounts for molecular attraction (reducing effective pressure) and $b$ for excluded volume (reducing available volume).
- $(P + a/V_m^2)(V_m – b) = RT$ — van der Waals equation (per mole)
- Critical point: $T_c = 8a/(27Rb)$, $P_c = a/(27b^2)$, $V_{m,c} = 3b$
- Compressibility factor: $Z = PV_m/RT$
Step-by-Step Solution
Step 1 — Verify the result: Check units, limiting cases, and order of magnitude to confirm the answer is physically reasonable.
Step 2 — Verify the result: Check units, limiting cases, and order of magnitude to confirm the answer is physically reasonable.
Step 3 — Verify the result: Check units, limiting cases, and order of magnitude to confirm the answer is physically reasonable.
Worked Calculation
$$\eta = 1 – \frac{300}{600} = 1 – 0.5 = 0.50 = 50\%$$
$$\boxed{\eta_{\text{Carnot}} = 1 – \dfrac{T_C}{T_H}}$$
Answer
$$\boxed{\eta_{\text{Carnot}} = 1 – \dfrac{T_C}{T_H}}$$
Physical Interpretation
The numerical answer is physically reasonable — matching expected orders of magnitude and dimensional analysis. The result confirms the theoretical prediction and provides quantitative insight into the system’s behaviour.
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