HCV Ch24 P1 – Kinetic Theory: RMS Speed of Gas Molecules

Problem Statement

Solve the kinematics problem: Find the rms speed of hydrogen molecules at 300 K. ($M_{H_2} = 2 \times 10^{-3}$ kg/mol, $R = 8.314$ J/mol·K) $T = 300$ K $M = 2 \times 10^{-3}$ kg/mol (molar mass of H₂) $R = 8.314$ J/mol·K The rms speed comes from equating kinetic energy to thermal energy: $$v_{rms} = \sqrt{\frac{3RT}{M}}$$ This i

Given Information

  • Initial velocity $u$ (or $v_0$)
  • Acceleration $a$ (constant unless stated otherwise)
  • Time $t$ or distance $s$ as given

Physical Concepts & Formulas

Kinematics describes motion without reference to its cause. For constant acceleration, the four SUVAT equations are sufficient to solve any problem. They follow directly from the definitions of velocity ($v = ds/dt$) and acceleration ($a = dv/dt$). For 2D problems (projectile motion), the horizontal and vertical motions are independent — horizontal: constant velocity; vertical: constant acceleration $g$ downward. Relative motion problems require defining a reference frame explicitly and using vector subtraction.

  • $v = u + at$
  • $s = ut + \tfrac{1}{2}at^2$
  • $v^2 = u^2 + 2as$
  • $s = \tfrac{1}{2}(u+v)t$
  • Range of projectile: $R = \dfrac{u^2\sin 2\theta}{g}$
  • Max height: $H = \dfrac{u^2\sin^2\theta}{2g}$

Step-by-Step Solution

Step 1 — List knowns and unknown: $u$, $v$, $a$, $s$, $t$ — identify which three are known.

Step 2 — Choose the SUVAT equation that contains the unknown and all three known quantities.

Step 3 — Substitute and solve algebraically.

Step 4 — For 2D: Decompose $\vec{u}$ into $u_x = u\cos\theta$, $u_y = u\sin\theta$. Solve $x$ and $y$ separately.

Worked Calculation

Substituting all values with units:

Projectile at $u = 20\,\text{m/s}$, $\theta = 30°$:

$$R = \frac{u^2\sin 2\theta}{g} = \frac{400\times\sin 60°}{9.8} = \frac{400\times0.866}{9.8} = \frac{346.4}{9.8} \approx 35.3\,\text{m}$$

$$H = \frac{u^2\sin^2\theta}{2g} = \frac{400\times0.25}{19.6} = \frac{100}{19.6} \approx 5.1\,\text{m}$$

Answer

$$\boxed{R = \dfrac{u^2\sin 2\theta}{g},\quad H = \dfrac{u^2\sin^2\theta}{2g}}$$

Physical Interpretation

Maximum range occurs at $\theta = 45°$ where $\sin 90°=1$. The complementary angles $30°$ and $60°$ give the same range — a 20 m/s ball at either angle reaches ~35 m. Athletes intuitively throw at 45° for distance. The horizontal range is quadratic in $u$, so doubling the speed quadruples the range.


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