Problem Statement
For a 3s electron in Na ($Z=11$), estimate the effective nuclear charge using Slater’s rules.
Given Information
- All quantities, constants, and constraints stated in the problem above
- Physical constants used as needed (see Concepts section)
Physical Concepts & Formulas
This problem draws on fundamental physical principles. The key is to identify which conservation law or field equation governs the system, then apply it systematically. Dimensional analysis can always be used to verify that the final answer has the correct units. Working from first principles — rather than memorising formulas — builds deeper understanding and allows tackling novel problems.
- Identify the relevant physical law (Newton’s laws, conservation of energy/momentum, Maxwell’s equations, etc.)
- State the mathematical form of that law as it applies here
- Check dimensions at every step: both sides of an equation must have the same units
Step-by-Step Solution
Problem Statement
For a 3s electron in Na ($Z=11$), estimate the effective nuclear charge using Slater’s rules.
Given Information
- All quantities, constants, and constraints stated in the problem above
- Physical constants used as needed (see Concepts section)
Physical Concepts & Formulas
This problem draws on fundamental physical principles. The key is to identify which conservation law or field equation governs the system, then apply it systematically. Dimensional analysis can always be used to verify that the final answer has the correct units. Working from first principles — rather than memorising formulas — builds deeper understanding and allows tackling novel problems.
- Identify the relevant physical law (Newton’s laws, conservation of energy/momentum, Maxwell’s equations, etc.)
- State the mathematical form of that law as it applies here
- Check dimensions at every step: both sides of an equation must have the same units
Step-by-Step Solution
For a 3s electron in Na ($Z=11$), estimate the effective nuclear charge using Slater’s rules.
Solution
Slater’s rules for effective nuclear charge $Z_{eff} = Z – S$:
Na configuration: $1s^2 2s^2 2p^6 3s^1$
For the 3s electron, contributions to screening constant $S$:
- Other electrons in same group $(3s)$: 0 (no other 3s electrons)
- Electrons in $(2s,2p)$ group: $8\times0.85 = 6.80$
- Electrons in $(1s)$ group: $2\times1.00 = 2.00$
$$S = 6.80 + 2.00 = 8.80$$
$$Z_{eff} = 11 – 8.80 = 2.20$$
The 3s electron sees an effective charge of $Z_{eff} = 2.20$, much less than the nuclear charge of 11. This greatly reduces the binding energy.
Estimated 3s energy: $E \approx -Z_{eff}^2\times13.6/(3)^2 = -2.20^2\times1.51 = -7.31$ eV (actual: -5.14 eV; Slater’s rules are approximate)
Worked Calculation
Substituting all given numerical values with their units into the derived formula:
$$\text{Numerical result} = \text{given expression substituted with values}$$
Answer
$$\boxed{Z_{eff} = 11 – 8.80 = 2.20}$$
Physical Interpretation
The answer should be checked for dimensional consistency and physical reasonableness: is the magnitude in the expected range for this type of problem? Does the answer change in the correct direction when parameters are varied (e.g., increasing mass should increase momentum, increasing distance should decrease field strength)? These sanity checks are as important as the calculation itself.
Worked Calculation
Substituting all given numerical values with their units into the derived formula:
$$\text{Numerical result} = \text{given expression substituted with values}$$
Answer
$$\boxed{\boxed{Z_{eff} = 11 – 8.80 = 2.20}}$$
Physical Interpretation
The answer should be checked for dimensional consistency and physical reasonableness: is the magnitude in the expected range for this type of problem? Does the answer change in the correct direction when parameters are varied (e.g., increasing mass should increase momentum, increasing distance should decrease field strength)? These sanity checks are as important as the calculation itself.
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