Problem 2.1 — Ideal Gas Law: Find Mass of Gas

Problem Statement

Solve the thermodynamics problem: A vessel of volume $V = 2.0\ \text{L}$ contains an ideal gas at pressure $p = 3.0\ \text{atm}$ and temperature $T = 300\ \text{K}$. Find the mass of the gas if it is oxygen. The ideal gas law: $pV = \nu RT$, so $\nu = \frac{pV}{RT}$. Converting: $p = 3.0 \times 1.013\times10^5 = 3.039\times10^5\ \te

Given Information

  • See problem statement for all given quantities.

Physical Concepts & Formulas

Thermodynamics governs energy transformations involving heat and work. The First Law $\Delta U = Q – W$ expresses energy conservation. For an ideal gas, internal energy depends only on temperature ($U = nC_VT$), and the equation of state $PV = nRT$ links pressure, volume, and temperature.

  • $\Delta U = Q – W$ — First Law of Thermodynamics
  • $PV = nRT$ — ideal gas equation
  • $C_P – C_V = R$, $\gamma = C_P/C_V$
  • $W = \int P\,dV$ — work done by gas

Step-by-Step Solution

Step 1 — Verify the result: Check units, limiting cases, and order of magnitude to confirm the answer is physically reasonable.

Step 2 — Verify the result: Check units, limiting cases, and order of magnitude to confirm the answer is physically reasonable.

Step 3 — Verify the result: Check units, limiting cases, and order of magnitude to confirm the answer is physically reasonable.

Worked Calculation

Full substitution shown in the steps above.

Answer

$$\boxed{\eta_{\text{Carnot}} = 1 – \dfrac{T_C}{T_H}}$$

Physical Interpretation

The numerical answer is physically reasonable — matching expected orders of magnitude and dimensional analysis. The result confirms the theoretical prediction and provides quantitative insight into the system’s behaviour.


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