Problem Statement
The $2s$ and $2p$ states of hydrogen are degenerate in the Bohr model but split in reality. Explain the Lamb shift.
Given Information
- All quantities, constants, and constraints stated in the problem above
- Physical constants used as needed (see Concepts section)
Physical Concepts & Formulas
This problem draws on fundamental physical principles. The key is to identify which conservation law or field equation governs the system, then apply it systematically. Dimensional analysis can always be used to verify that the final answer has the correct units. Working from first principles — rather than memorising formulas — builds deeper understanding and allows tackling novel problems.
- Identify the relevant physical law (Newton’s laws, conservation of energy/momentum, Maxwell’s equations, etc.)
- State the mathematical form of that law as it applies here
- Check dimensions at every step: both sides of an equation must have the same units
Step-by-Step Solution
The $2s$ and $2p$ states of hydrogen are degenerate in the Bohr model but split in reality. Explain the Lamb shift.
Solution
In the pure Coulomb potential, all states with the same $n$ are degenerate regardless of $l$. However, quantum electrodynamics (QED) predicts:
- Lamb shift: Vacuum fluctuations of the electromagnetic field cause a small energy shift, lifting the $2s$-$2p$ degeneracy. The $2s_{1/2}$ level is shifted up by $\Delta E \approx 1057$ MHz relative to $2p_{1/2}$.
- This was first measured by Lamb and Retherford in 1947 using microwave spectroscopy.
- The $2s$ state is metastable (lifetime $\sim 0.1$ s) because the $2s\to1s$ transition is electric-dipole forbidden ($\Delta l = 0$).
Answer: Lamb shift $\approx 1057$ MHz; $\Delta E \approx 4.4\times10^{-6}$ eV
Worked Calculation
Substituting all given numerical values with their units into the derived formula:
$$\text{Numerical result} = \text{given expression substituted with values}$$
Answer
$$\boxed{\Delta E \approx 4.4\times10^{-6}}$$
Physical Interpretation
The answer should be checked for dimensional consistency and physical reasonableness: is the magnitude in the expected range for this type of problem? Does the answer change in the correct direction when parameters are varied (e.g., increasing mass should increase momentum, increasing distance should decrease field strength)? These sanity checks are as important as the calculation itself.
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